Pdf analysis of residual products in benzyl chloride used for the. The data provided in this material safety data sheet is meant to represent typical dataanalysis for this product and is correct to the best of our knowledge. Benzyl chloride cas no 100447 manufacturers, suppliers. Show this safety data sheet to the doctor in attendance. First aid measures general advice consult a physician.
Aqua water eau sodium laureth sulfate glycerin cocamidopropyl betaine sodium chloride glycereth2 cocoate benzyl alcohol ethylhexylglycerin tocopherol. Chemical product and company identification product name. Uses advised against food, drug, pesticide or biocidal product use. Next to the blood, benzyl chloride was present in the adipose tissue and no concentrations of benzyl chloride found in the brain, lungs, pancreas and testis. The benzyl chloride may also be isolated by distillation under atmospheric pressure. Firstaid measures general advice show this safety data sheet to the doctor in attendance. In the atmosphere, benzyl alcohol is expected to exist almost entirely in the vapor phase. List i and ii regulated chemicals alphabetical order 21feb20 page 2 of 2. The acute shortterm effects of benzyl chloride from inhalation exposure in humans consist of severe irritation of the upper respiratory tract, skin, eyes, and. Precautionary statements p260 do not breathe dust fume gas mist vapours spray. Carbobenzoxy chloride, z chloride cas number 501531. Be careful with do it yourself products such as wet and forget that you can purchase at the store. Sds of benzyl chloride, safety data sheets, cas 100447.
Material safety data sheet benzyl chloridesection 6 accidental release measures small spill. This product has been classified in accordance with the hazard criteria of the controlled products regulations and the msds contains all of the information. Benzyl chloride has been used as an irritant gas in chemical. Potassium chloride 7447 40 7 listed on the united states tsca toxic substances control act inventory all components of this product are listed, or excluded from listing, on the united states environmental protection agency toxic substances control act tsca inventory 15. Vinyl benzyl chloride is not listed on the tsca inventory. If inhaled if breathed in, move person into fresh air. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Vinylbenzyl chloride is a monomer that can be reacted with other materials before or after polymerization. Pdf single pot benzylation of oxylene with benzyl chloride and. We ask that users who download significant portions of the database cite the. Pictogram signal word danger hazard statements h302 harmful. Analysis of residual products in benzyl chloride used for the industrial synthesis of quaternary compounds by liquid chromatography with diodearray detection. Sigmaaldrich material safety data sheet product name benzyl. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only.
Consumer exposure lanxess does not sell benzyl alcohol to the general public. Very little benzyl chloride was present in the blood 4 hr after termination of exposure. May contain trace levels of acetaldehyde, benzene, benzyl chloride, 1,4dioxane, ethylene oxide, nnitrosodimethylamine, propylene oxide and toluene. Benzyl chloride can be used in the manufacture of synthetic tannins and as a gum inhibitor in petrol. The data was obtained from current and reliable sources, but is supplied without warranty, expressed or implied, regarding its correctness or accuracy. The resulting benzyl chloride is, however, of lower purity unless a fractionating column is used. Ethyl benzyl chloride get medical attention immediately. The information given is designed only as a guidance for safe handling, use, processing, storage. Benzyl chloride reacts with aqueous sodium hydroxide to give dibenzyl ether. See actual entry in rtecs for complete information. As sold by dow, vinylbenzyl chloride monomer is a mixture of 57 percent metaisomer and 43 percent paraisomer. Benzyl chloride is used as a chemical intermediate in the manufacture of certain dyes and pharmaceutical, perfume and flavor products.
Pdf analysis of residual products in benzyl chloride. Benzyl chloride cas no 100447 material safety data sheet sdsmsds. Benzoyl chloride liquid is corrosive, and can cause redness, pain, and burns on contact with skin and eyes. At least one mold, moss and mildew stain remover contains benzyl ammonium chloride also known as benzalkonium chloride. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy.
Spray cavicide so as to thoroughly drench all instrument surfaces and allow to remain visibly wet for 30 seconds. List i and ii regulated chemicals alphabetical order list dea effective. A corrosion inhibitor is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy. International regulations canada potassium chloride 7447 40 7. Material safety data sheet vital oxide wintersteiger. Benzyl ethers are often derived from benzyl chloride. Benzyl chloroformate 501531 98 constituents chemical name cas number % benzyl chloride 100447 benzyl chloride 100447 95 propylene oxide 75569 0. Except where otherwise noted, data are given for materials in their standard state at 25 c 77 f, 100 kpa. Synonyms alkyl benzyl dimethylammonium chloride recommended use laboratory chemicals. Nucleophilic substitution sulfonation in emulsions.
Follow with appropriate cleaning and disinfection process. Hazardous substances data bank hsdb, online database. Extremely hazardous substances ehs chemical profiles and emergency first aid. Mkaibosh june, 2007 page 4 of 4 center telephone 18004248802 in the event of a release of quantities of the following hazardous materials contained in this product, if the release is equal to or greater than the reportable quantities rqs. P280 wear protective gloves protective clothing eye protection face protection. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided. Benzyl bromide not listed as a carcinogen by acgih, iarc, ntp, or ca prop 65. Sigmaaldrich material safety data sheet date printed. The main sources of information for this fact sheet are epas integrated. Our team of scientists has experience in all areas of research including life science, material science, chemical synthesis, chromatography, analytical and many others.
Corrosion inhibitor57 is an alkylpyridine quaternary. A mixture of benzyl alcohol and 58% sulfuric acid decomposed violently when heated to 180c. Benzyl chloride is the aromatic halogencontaining compound that conforms to the formula. Benzyl chloride 100447 hazard summary benzyl chloride is used as a chemical intermediate in the manufacture of certain dyes and pharmaceutical products and as a photographic developer. Home cas database listed 9 benzoyl chloride material safety data sheetmsds cas no. Eye contact rinse immediately with plenty of water, also. Special hazards arising from the substance or mixture fire hazard. Material safety data sheet kaibosh kaivac, incorporated trade name. The benzyl chloride manufacturing companies are offering top quality products. Material safety data sheet benzyl chloride section 6 accidental release measures small spill. Here you will find the database of benzyl chloride cas no 100447, benzyl chloride manufacturers, benzyl chloride suppliers and exporters.
Material safety data sheet kaibosh kaivac, incorporated. If released to water, benzyl alcohol is expected to undergo microbial degradation under aerobic and anaerobic conditions. Hazardous decomposition products formed under fire conditions. Benzyl bromide was sulfonated at 298 k in emulsions formed with dioctyldimethylammonium bromide, or chloride.
This substance was neither included in the first list in 1998 nor the second list in 2000, but was included in the third list in 2004 and ha s. When stabilized with propylene oxide, the possibility of a friedelcrafts type reaction is minimized. Allyl chloride safety data sheet 06252015 en english us sds id. Other information the information on this sheet is not a specification and does not guarantee specific properties. Benzyl chloride 100447 60 100% all concentrations are percent by weight unless ingredient is a gas. Halogenated organics generally become less reactive as more of their hydrogen atoms are replaced with halogen atoms. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.
Details of the supplier of the safety data sheet emergency telephone number for information us call. Benzyl chloride c6h5ch2cl or c7h7cl cid 7503 structure, chemical. Materials in this group are incompatible with strong oxidizing and reducing agents. Remove victim to fresh air and keep at rest in a position comfortable for breathing. The reaction between the cellulosic hydroxyl group of the fiber and benzyl chloride is. Friedelcrafts acylation of naphthalene using benzoyl chloride, catalyzed by alcl3, must be conducted above the melting point of the mixture, or the. Spray cavicide directly onto precleaned surface, thoroughly wetting area to be. In organic synthesis, benzyl chloride is used to introduce the benzyl protecting group in reaction with alcohols, yielding the corresponding benzyl ether, carboxylic acids, and benzyl ester. This msds was prepared and is to be used only for this product. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Benzyl chloride material safety data sheet cas no 100447. Certain materials may be made available for download from the echa website such as lists, search results. Ammonium, alkyl dimethyl benzyl, chloride 8001545 no data available 4850 3. Qualitative and quantitative composition sodium chloride benzyl alcohol water for injection 3.
The material boiling between 175c and 185c is collected and redistilled, the final product is collected at 178182c pure benzyl chloride has bp 179c. Halogenated aliphatic compounds, such as benzyl chloride, are moderately or very reactive. Hydrolyzes very slowly to form hydrogen chloride and benzyl alcohol. Spray cavicide directly onto precleaned surface, thoroughly wetting area to be treated. Safety data sheet northwest missouri state university. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Enter synonyms, trade names or additional information. Search results for benzyl chloride at sigmaaldrich. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Find msds or sds, a coa, data sheets and more information. Benzyl chloride is used as a chemical intermediate in the manufacture of certain dyes and. Safety data sheet according to 29cfr19101200 and ghs rev. View enhanced pdf access article on wiley online library html view download pdf for offline viewing. Corrosion inhibitor57 is an alkylpyridine quaternary ammonium chloride used to formulate corrosion inhibitors used in drilling, completion, production and water floods. Benzyl chloride material safety data sheet cas no 100. Benzyl alcohol is naturally occurring in many plants and is commonly found in fruits and teas.
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